Stereoselective total synthesis of (-)-cleistenolide.
نویسندگان
چکیده
A facile stereoselective total synthesis of cleistenolide (1) from the natural chiral template d-arabinose has been achieved in eight steps and 49% overall yield, employing key steps including Wittig olefination, selective 1,3-trans-acetal formation, and modified Yamaguchi esterification.
منابع مشابه
STEREOSELECTIVE SYNTHESIS OF METHYL TETRA-0-METHYL a-AND P-D-GLUCO-AND MANNOPYRANOSIDES
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 75 16 شماره
صفحات -
تاریخ انتشار 2010